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Methanol

CH

4

O

CAS-No: 67-56-1

EC-No: 200-659-6

EC index No: 603-001-00-X

M= 32.04 g/mol

Vapor Pressure: 128 hPa (20°C)

Specific density: 0.792 g/cm

3

(20°C)

Flash point: 10°C

Soluble in H

2

O soluble at 20°C

pH value -

Melting point: -98°C

Bulk density: -

Boiling point: 64.5°C (1013 hPa)

Ignition temperature: 455°C

Explosive limit: 5.5 - 44 %(V)

Viscosity kinematic: -

Flammable, Toxic

H-STATEMENT/EUH: H225;301+311+331;

370 / P210;240;280;302+352;304+340; 308+

310;403+233

Test Type: LD50 Dermal Rabbit

Results: 15800 mg/kg

HS-CODE: 2905 11 00 LGK: 3

Disposal: 1 WGK: 1 UN: 1230

947.046

Methanol -

ACS Reagent, Reag. ISO, Reag. Ph. Eur.

Specification

Purity (GC area %)

99.8 - 100 %

Appearance

Colorless liquid

Solubility (turbidity)

Mixable with H

2

O

Water (coulometr.)

0.05 %

Residue (evaporation)

0.0005 %

Reducing substances (as O)

0.00025 %

Aldehydes (ASCH

3

CH)

0.001 %

Ketones (ASCH

3

COCH

3

)

0.001 %

Formaldehyde

0.001 %

Acetaldehyde

0.001 %

Aluminium (ICP)

0.00005 %

Barium (ICP)

0.00001 %

Bismuth (ICP)

0.00001 %

Boron (ICP)

0.000002 %

Calcium (ICP)

0.00005 %

Cadmium (ICP)

0.000005 %

Cobalt (ICP)

0.000002 %

Chromium (ICP)

0.000002 %

Copper (ICP)

0.000001 %

Iron (ICP)

0.00001 %

Potassium (ICP)

0.00005 %

Color (APHA)

10

Lithium (ICP)

0.00001 %

Magnesium (ICP)

0.00001 %

Manganese (ICP)

0.000001 %

Molybdenum (ICP)

0.00001 %

Sodium (ICP)

0.00005 %

Nickel (ICP)

0.000002 %

Lead (ICP)

0.000002 %

Tin (ICP)

0.00001 %

Strontium (ICP)

0.00001 %

Zinc (ICP)

0.00001 %

Free acid (as HCOOH)

0.002 %

Chloride (Cl)

0.00005 %

Sulfate (SO

4

)

0.0001 %

Substances dark by H

2

SO

4

passes test

Carbonyl compounds

0.005 %

Free alkali (as NH

3

)

0.00005 %

Acetone

0.001 %

Ethanol

0.1 %

catalogue

number

947.046.2500

packing

specs

plastic bottle

pack

in box

4 pieces

volume

in pack

2.5 l

947.048

Methanol -

LC-MS

Specification

Assay (GC)

99.90%

Appearance

Clear colorless liquid

Color (APHA)

10

Residue after evaporation

0.0005%

Water (KF)

0.02%

Acidity (as HCOOH)

0.001%

Alkalinity (as NH

3

)

0.0005%

Silver (Ag)

0.00001%

Aluminium (Al)

0.00005%

Barium (Ba)

0.00001%

Calcium (Ca)

0.00001%

Cadmium (Cd)

0.000005%

Cobalt (Co)

0.000002%

Chromium (Cr)

0.000002%

Copper (Cu)

0.000001%

Iron (Fe)

0.00001%

Potassium (K)

0.00001%

Magnesium (Mg)

0.00001%

Manganese (Mn)

0.000001%

Sodium (Na)

0.00001%

Nickel (Ni)

0.000002%

Lead (Pb)

0.000002%

Tin (Sn)

0.00001%

Zinc (Zn)

0.00001%

Absorbance at 210 nm

0.523AU

Absorbance at 220 nm

0.301AU

Absorbance at 230 nm

0.125AU

Absorbance at 260 nm

0.009AU

F254 nm (as Quinine)

0.0000001%

F365 nm (as Quinine)

0.0000001%

Grad. elution H.Peak at 254 nm 1mAU

Suitability for the LC-MS

passes test

catalogue

number

947.048.2501

packing

specs

glass bottle

pack

in box

4 pieces

volume

in pack

2.5 l

947.047

Methanol -

For liquid chromatography

Specification

Purity (GC)

99.9 %

Identity (IR)

passes test

Evaporation residue

0.0003 %

Water

0.03 %

Colour

10 Hazen

Acidity

0.0002meq/g

Alkalinity

0.0002meq/g

Transmission (at 225 nm)

50 %

Transmission (at 240 nm)

80 %

Transmission (at 265 nm)

98 %

Fluorescence 254 nm

0.0000001 %

Fluorescence 365 nm

0.0000001 %

Filtered by 0.2 µm filter.

catalogue

number

947.047.2501

packing

specs

glass bottle

pack

in box

4 pieces

volume

in pack

2.5 l

947.043

Methanol -

Ph Eur, BP, JPE, NF

Specification

Assay (GC)

99.7%

Refractive index (n 20/D)

1.328 - 1.330

Non-volatilematter

0.001%

Water (Karl Fischer)

0.10%

Acidity or alkalinity

passes test

Free acid (as HCOOH)

0.003%

Free alkali (as NH

3

)

0.0003%

Iron (Fe)

0.0001%

Identity (IR)

passes test

Chloride (Cl)

0.0001%

Sulfate (SO

4

)

0.0005%

Reaction against H

2

SO

4

passes test

Reducing impurities

passes test

Aldehydes, ketones (as CH

3

COCH

3

) 0.003%

Acetone (GC)

0.001%

UV-absorption

passes test

Related substance (GC)

passes test

Appearance

passes test

Residual solvents

passes test

catalogue

number

947.043.2500

packing

specs

plastic bottle

pack

in box

4 pieces

volume

in pack

2.5 l